Solutions Chemistry Online Mock Test: NEET PYQBy admin / March 12, 2025 Class 12 Chemistry Online Free Mock Test 5/5 - (1 vote) 0% 9 Report a question What’s wrong with this question? You cannot submit an empty report. Please add some details. Solutions Chemistry Online Mock Test: NEET PYQ 1 / 21 1. The mixture that forms maximum boiling azeotrope is (NEET 2019) A. heptane + octane B. water + nitric acid C. ethanol + water D. acetone + carbon disulphide 👉 Short Explanation 👉 Maximum boiling azeotrope forms when: Solution shows negative deviation from Raoult’s law Strong intermolecular attractions → lower vapour pressure → higher boiling point ✔ Water + nitric acid shows strong interactions ⇒ negative deviation ❌ Ethanol + water → positive deviation (minimum boiling azeotrope) ✔ Correct Answer: (B) 2 / 21 2. The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is (NEET-II 2016) A. 0 B. 1 C. 2 D. 3 3 / 21 3. Which of the following is dependent on temperature? (NEET 2017) A. Molarity B. Mole fraction C. Weight percentage D. Molality 👉 Short Explanation 👉 Molarity (M) depends on volume of solution, and volume changes with temperature ✔ So, molarity changes with temperature ❌ Others: Mole fraction → based on moles (no volume) Weight % → based on mass Molality → moles per kg solvent 👉 These are temperature independent ✔ Correct Answer: (A) Molarity 4 / 21 4. Which one of the following is incorrect for ideal solution? (NEET-II 2016) A B C D 5 / 21 5. The mixture which shows positive deviation from Raoult's law is (2020) A. Benzene + Toluene B. Acetone + Chloroform C. Chloroethane + Bromoethane D. Ethanol + Acetone 👉 Short Explanation 👉 Positive deviation occurs when: A–B interactions are weaker than A–A or B–B Vapour pressure increases ✔ Ethanol + Acetone: Breaks strong H-bonding in ethanol Forms weaker interactions ⇒ positive deviation ❌ Others: Benzene + Toluene → ideal solution Acetone + Chloroform → strong H-bonding ⇒ negative deviation Chloroethane + Bromoethane → nearly ideal ✔ Correct Answer: (D) 6 / 21 6. Mass of glucose (C₆H₁₂O₆) required to be dissolved to prepare one litre of its solution which is isotonic with 15 g L⁻¹ solution of urea (NH₂CONH₂) is (Given: Molar mass in g mol⁻¹ C:12, H:1, O:16, N:14) [NEET 2024 Rel] A. 55 g B. 15 g C. 30 g D. 45 g 7 / 21 7. In water saturated air, the mole fraction of water vapour is 0.02. If the total pressure of the saturated air is 1.2 atm, the partial pressure of dry air is (Odisha NEET 2019) A. 1.18 atm B. 1.76 atm C. 1.176 atm D. 0.98 atm 8 / 21 8. The density of the solution is 2.15 g mL⁻¹, then mass of 2.5 mL solution in correct significant figures is: [NEET Re-2022] A. 53.75 g B. 5375 × 10⁻³ g C. 5.4 g D. 5.38 g Solution: In case of multiplication and division, the final result should be reported as having the same number of significant digits as the number with least number of significant digits. 9 / 21 9. The plot of osmotic pressure (π) vs concentration (mol L⁻¹) for a solution gives a straight line with slope 25.73 L bar mol⁻¹. The temperature at which the osmotic pressure measurement is done is (Use R = 0.083 L bar mol⁻¹ K⁻¹) [NEET 2024] A. 37°C B. 310°C C. 25.73°C D. 12.05°C 10 / 21 10. Arrange the following compounds in increasing order of their solubilities in chloroform: [NEET 2024 Rel] NaCl, CH₃OH, cyclohexane, CH₃CN A. NaCl < CH₃CN < CH₃OH < CyclohexaneB. CH₃OH < CH₃CN < NaCl < CyclohexaneC. NaCl < CH₃OH < CH₃CN < CyclohexaneD. Cyclohexane < CH₃CN < CH₃OH < NaCl A B C D 👉 Short Explanation: 👉 Chloroform (CHCl₃) is non-polar / slightly polar solvent Rule: “Like dissolves like” NaCl → ionic ⇒ least soluble ❌ CH₃CN → polar ⇒ low solubility CH₃OH → polar but has some compatibility ⇒ moderate Cyclohexane → non-polar ⇒ most soluble ✔ 👉 Increasing order: NaCl<CH3CN<CH3OH<Cyclohexane ✔ Correct Answer: (A) 11 / 21 11. For an ideal solution, the correct option is (NEET 2019) A. ΔG𝑚𝑖𝑥 = 0 at constant T and P B. ΔS𝑚𝑖𝑥 = 0 at constant T and P C. ΔV𝑚𝑖𝑥 =/= 0 at constant T and P D. Δ𝐻𝑚𝑖𝑥 = 0 at constant T and P 👉 Short Explanation For an ideal solution: ✔ ΔHmix=0 → no heat absorbed or evolved✔ ΔVmix=0 → no volume change✔ ΔSmix>0 → randomness increases✔ ΔGmix<0 → spontaneous mixing 👉 Only correct statement: ΔHmix=0 ✔ Correct Answer: (D) 12 / 21 12. The following solutions were prepared by dissolving 10 g of glucose (C₆H₁₂O₆) in 250 mL of water (P₁), 10 g of urea (CH₄N₂O) in 250 mL of water (P₂) and 10 g of sucrose (C₁₂H₂₂O₁₁) in 250 mL of water (P₃). The right option for the decreasing order of osmotic pressure of these solutions is: [NEET 2021] A. P₂ , P₁ , P₃ B. P₁ , P₂ , P₃ C. P₂ , P₃ , P₁ D. P₃ , P₁ , P₂ Solution: Osmotic pressure (π) = iCRT where C is molar concentration of the solution With increase in molar concentration of solution osmotic pressure increases. Since, weight of all solutes and its solution volume are equal, so higher will be the molar mass of solute, smaller will be molar concentration and smaller will be the osmotic pressure. Order of molar mass of solute decreases asSucrose > Glucose > Urea So, correct order of osmotic pressure of solutions: P3<P1<P2 13 / 21 13. The Henry's law constant (Kₕ) values of three gases (A, B, C) in water are 145, 2 × 10⁻⁵ and 35 kbar, respectively. The solubility of these gases in water follow the order(decreasing order): [NEET 2024] B , A , C B , C , A A , C , B A , B , C 14 / 21 14. In one molal solution that contains 0.5 mole of a solute, there is [NEET-2022] A. 500 mL of solvent B. 500 g of solvent C. 100 mL of solvent D. 1000 g of solvent Solution: Molality is the moles of solute dissolved per kg of solvent therefore 500g, 1 molal solution contains 0.5 of solute, as 15 / 21 15. Which of the following statements is correct regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour? (Odisha NEET 2019) A. Intermolecular attractive forces between A–A and B–B are stronger than those between A–B B. ΔHmix =0 at constant T and P C. ΔVmix =0 at constant T and P D. Intermolecular attractive forces between A–A and B–B are equal to those between A–B 👉 Short Explanation 👉 Positive deviation from Raoult’s law occurs when: A–B interactions are weaker than A–A and B–B Molecules escape easily ⇒ vapour pressure increases ✔ So statement (A) is correct ❌ (B), (C), (D) → true for ideal solution, not positive deviation ✔ Correct Answer: (A) 16 / 21 16. Gas: KH / K.bar Ar → 40.3, CO₂ → 1.67, HCHO → 1.83×10−5, CH₄ → 0.413 Where KH is Henry's Law constant in water. The order of their solubility in water is: [NEET Re-2022] A. HCHO < CH₄ < CO₂ < ArB. Ar < CO₂ < CH₄ < HCHOC. CO₂ < Ar < CH₄ < HCHOD. HCHO < CO₂ < CH₄ < Ar A B C D Solution: ✔ Correct Answer: (B) 17 / 21 17. If molality of the dilute solution is doubled, the value of molal depression constant (Kf) will be (NEET 2017) A. halved B. tripled C. unchanged D. doubled 👉 Short Explanation 👉 Kf (molal depression constant) is a property of the solvent only It does NOT depend on concentration (molality) It remains constant for a given solvent ✔ Even if molality is doubled → Kf remains same ✔ Correct Answer: (C) unchanged 18 / 21 18. During the preparation of Mohr's salt solution (Ferrous ammonium sulphate), which of the following acid is added to prevent hydrolysis of Fe²⁺ ion? [NEET 2024] A. dilute hydrochloric acid B. concentrated sulphuric acid C. dilute nitric acid D. dilute sulphuric acid 👉 Short Explanation: 👉 Fe²⁺ ions undergo hydrolysis in water forming Fe(OH)₂. To prevent this, solution is kept slightly acidic. ✔ Dilute H₂SO₄ is used because: Provides acidic medium Does NOT oxidize Fe²⁺ (unlike HNO₃) ✔ Correct Answer: (D) dilute sulphuric acid 19 / 21 19. The correct option for the value of vapour pressure of a solution at 45°C with benzene to octane in molar ratio 3 : 2 is: [At 45°C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume ideal solution] [NEET 2021] A. 160 mm of Hg B. 168 mm of Hg C. 336 mm of Hg D. 350 mm of Hg 20 / 21 20. The freezing point depression constant (Kf) of benzene is 5.12 K kg mol⁻¹. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is (rounded off up to two decimal places): (2020) A. 0.80 K B. 0.40 K C. 0.60 K D. 0.20 K 5.12 × 0.078 = 0.399K = 0.40K 21 / 21 21. Which amongst the following aqueous solution of electrolytes will have minimum elevation in boiling point? Choose the correct option :- [NEET 2023 mpr] A. 0.05 M NaCl B. 0.1 M KCl C. 0.1 M MgSO₄ D. 1 M NaCl 👉 Short Explanation Elevation in boiling point: ΔTb=iKbm 👉 Depends on van’t Hoff factor (i) × concentration (m) ✔ Correct Answer: (A) 0.05 M NaCl Your score isThe average score is 33% 0% Restart quiz Post Views: 22
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