Chemical Kinetics Class 12 Chemistry Free Online Mock Test 1By admin / March 12, 2025 Class 12 Chemistry Online Free Mock Test Rate this post Chemical Kinetics Online Mock Test Class 12 Chemistry 1 / 25 1 2 3 4 2 / 25 1 2 3 4 3 / 25 1 2 5/3 0 4 / 25 In 30 minutes, a first-order reaction is 50% complete. Calculate the amount of time it took to complete 87.5 percent of the reaction. a) 30 minutes b) 60 minutes c) 90 minutes d) 120 minutes Explanation: In 30 minutes, the reaction is 50% complete. As a result, t1/2 = 30 minutes. In two half-lives, 75% of the process is accomplished. As a result, t = 2 ×30 = 60 minutes. In three half-lives, 87.5 percent of the reaction is finished. Hence, t = 3 × 30 = 90 minutes. 5 / 25 In a reaction, what is the driving force? a) Energy given b) Energy released c) Free energy d) None of the mentioned 6 / 25 2 1 1.5 Zero 7 / 25 If a reaction’s rate is represented as rate = k [A]² [B], the reaction’s order will be 1 2 3 4 8 / 25 A reaction’s rate constant is k=3.28 × 10-4 s-1. Determine the reaction’s order. a) First order b) Second order c) Third order d) Fourth order Answer-:: a)first order Explanation: Given that k= 3.28 × 10-4s-1 The standard formula for calculating rate constant units is k=(mol L-1)1-ns-1, where n is the order of the reaction. For (mol L-1)1-ns-1 to become s-1, the value of n must be 1. As a result, k=3.28 × 10-4s-1 denotes a first order reaction. 9 / 25 Dimethyl ether breakdown is a fractional order process. rate =k(PCH3OCH3)3/2 gives the rate. What are the units of rate and rate constant if pressure is measured in bars and time is measured in minutes? (a bar min-1, bar2 min-1 (b) bar min-1, bar1/2 min-1 (c) bar1/2 min-1, bar² min-1 (d) bar min-1, bar1/2 min-1 a b c d 10 / 25 The reaction NO2 + CO → NO + CO2 occurs in two steps. Locate the rate law. 2NO2 → NO + NO3 (k1) – slow NO3 + CO → CO2 + NO2 (k2) – fast a) R = k1 [NO2] ³ b) R = k2 [NO3] [CO] c) R = k1 [NO2] d) R = k1 [NO2]² a b c d Answer: d) R = k1 [NO2]² Explanation: In any reaction, the slowest step is the rate determining step; the overall reaction rate is determined by this step. As a result, the rate determining step is 2NO2= NO + NO3(k1). As a result, the rate rule R= k1[NO2]² . 11 / 25 Which of the following reactions is an example of a fractional order reaction? ((a) NH4NO2 → N2+ 2H2O (b) NO + O3→ NO2+ O2 (c) 2NO + Br2→ 2NOBr (d) CH3CHO → CH4+ CO a b c d 12 / 25 The rate constant for the reaction 2H2 + 2NO → 2H2O + N2 with rate = K|H2||NO|², is (a) mol L-1 s-1 (b) s-1 (c) mol-2  L² s-1 (d)mol L-1 a b c d 13 / 25 What is the rate law for acid hydrolysis of an ester in aqueous solution, such as CH3COOC2H5? a) k [CH3COOC2H5] b) k [CH3COOC2H5] [H2O] c) k [CH3COOC2H5]² d) k a b c d Explaination-: : Acid hydrolysis of ester, CH3COOC2H5 + H2O → CH3COOH + C2H5OH When one reactant is taken in excess of the other, the reaction’s sequence can be changed. Water is present in excess according to the rate law R= k [CH3COOC2H5] [H2O]. As a result, R=k [CH3COOC2H5]. 14 / 25 If the concentration of material X is doubled and that of Y is halved, how many times will the rate of the elementary reaction 3X + Y = X2Y change? a) r2= 4.5r1 b) r2= 5r1 c) r2= 2r1 d) r2= 4r1 a b c d Answer: d) r2= 4r1 Because it is an elementary reaction, the rate law r1= k [A]³[B] The new rate will be r2=k when the concentrations are changed r2= k (2[A])3([B]/2) = 4k[A]³[B] As a result, r2=4r1 15 / 25 A reaction’s rate constant is determined by (a) temperature of the reaction (b) extent of the reaction (c) initial concentration of the reactants (d) the time of completion of reaction Answer: (d) the time of completion of reaction Explanation-: The rate of reaction constant is determined by the time taken by the reaction is completed by time taken to completion of the whole reaction. 16 / 25 The chemical reaction, 2O3→ 3O2 Proceeds as O3 ⇌ O2+ |O| (fast) |O| + O3 → 2O2 (slow) The rate law expression will be (a) Rate = k [O] [O3] (b) Rate = k [O3]² [O2]-1 (c) Rate = k [O3]² (d) Rate = k [O2] [O] a b c d 17 / 25 For a given rate, the unit of rate and the rate constant are the same. (a) zero order reaction (b) first order reaction (c) second order reaction (d) third order reaction 18 / 25 The number of molecules of the reactants involved in a single stage of the reaction indicates (a) the order of the reaction (b) the molecularity of the reaction (c) the rapid step of the reaction mechanism, and (d) the reaction half-life. 19 / 25 For a unimolecular reaction, (a) the slowest step’s order and molecularity are both one (b) the reaction’s molecularity can be zero, one, or two; (c) the reaction’s molecularity can only be determined experimentally (d) more than one reacting species are engaged in one step. 20 / 25 The overall rate of a reaction is determined by (a) the rate of fastest intermediate step (b) the sum total of the rates of all intermediate steps (c) the average of the rates of all the intermediate steps (d) the rate of slowest intermediate step 21 / 25 A first order reaction has a half-life length of 10 minutes. In 100 minutes, what proportion of the response will be completed? ( a) 25% (b) 50% (c) 99.9% (d) 75% 22 / 25 For a 30 percent breakdown, a first order reaction takes 40 minutes. What will t1/2 be? (a) 77.7 min (b) 52.5 min (c) 46.2 min (d) 22.7 min 23 / 25 The rate constant of a first order reaction is 1.15 10-3s-1. How long will it take to decrease 5 g of this reactant to 3 g? (a) 444 seconds (b) 400 seconds (c) 528 seconds (d) 669 seconds 24 / 25 A straight line is drawn when log (a – x) is plotted against time t. This shows that the response is of order (a) zero (b) first (c) second (d) third 25 / 25 In a chemical reaction, the activation energy is defined as (a) the difference between the energies of the reactants and products, and (b) the sum of the energies of the reactants and products. (c) the difference between the average energy of reactants and products and the energy of the intermediate complex (d) the difference between the energy of the intermediate complex and the average energy of the reactants Your score isThe average score is 44% 0% Restart quiz Post Views: 21
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